五叠氮化砷

五叠氮化砷
识别
CAS号	399041-54-4
SMILES	[N-]=[N+]=N[As](N=[N+]=[N-])(N=[N+]=[N-])(N=[N+]=[N-])N=[N+]=[N-];
性质
化学式	As(N3)5
摩尔质量	285.02 g·mol⁻¹
外观	无色液体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五叠氮化砷是一种无机化合物，化学式为As(N₃)₅，它具有三角双锥构型，分子对称性为C_s。^[2]它的合成最初于2002年被报道，即可由五氟化砷和三甲基叠氮硅烷在二氧化硫中反应得到，^[3]并于2004年被成功分离。^[1]它和叠氮化四苯基鏻反应，可以得到[PPh₄][As(N₃)₆]。^[1]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N₃)₅, Sb(N₃)₅, and [P(C₆H₅)₄][Sb(N₃)₆]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730.
^ 葛忠学, 丁可伟, 李陶琦. 多叠氮化合物（页面存档备份，存于互联网档案馆）. 化学世界, 2012. 11: 965-700.
^ Karaghiosoff, Konstantin; Klapötke, Thomas M.; Krumm, Burkhard; Nöth, Heinrich; Schütt, Thomas; Suter, Max. Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species. Inorganic Chemistry (American Chemical Society (ACS)). 2001-12-22, 41 (2): 170–179. ISSN 0020-1669. doi:10.1021/ic010463l.

[angew-1] 1.0 ^1.1 ^1.2 Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N₃)₅, Sb(N₃)₅, and [P(C₆H₅)₄][Sb(N₃)₆]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730.

[hxsj-2] 葛忠学, 丁可伟, 李陶琦. 多叠氮化合物（页面存档备份，存于互联网档案馆）. 化学世界, 2012. 11: 965-700.

[3] Karaghiosoff, Konstantin; Klapötke, Thomas M.; Krumm, Burkhard; Nöth, Heinrich; Schütt, Thomas; Suter, Max. Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species. Inorganic Chemistry (American Chemical Society (ACS)). 2001-12-22, 41 (2): 170–179. ISSN 0020-1669. doi:10.1021/ic010463l.

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