二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂

二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂
识别
CAS号	194346-40-2
SMILES	[Cl-][Pt+2]([Cl-])([P]12CN3CN(CN(C3)C1)C2)[P]45CN6CN(CN(C6)C4)C5;
性质
化学式	H24Cl2N6P2Pt
摩尔质量	436.17 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二氯化二(1,3,5-三氮杂-7-磷杂金刚烷)合铂是一种配位化合物，化学式为PtCl₂P₂C₁₂H₂₄N₆。它可由四氯合铂(II)酸钾和1,3,5-三氮杂-7-磷杂金刚烷（PTA）在乙醇中反应制得，^[1]，或通过PtCl2(COD)（COD=1,5-环辛二烯）和PTA反应得到。^[2]它在0.1 mol/L的盐酸溶液中可以结晶出无色的cis-[PtCl₂(PTAH)₂]Cl₂晶体。^[1]它的配位氯可以被含硫配体取代。^[3]

参考文献

^ ^1.0 ^1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.¹ Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.
^ Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.
^ Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.

[ic-1] 1.0 ^1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.¹ Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.

[2] Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.

[3] Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.

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