氟氯碘甲烷是一種有機化合物，化學式為CHClFI，是三鹵代甲烷的一種，為手性分子[3]。它可由氯二碘甲烷和氟化汞反應得到。[2]在100 mmHg、110 °C加熱乾燥的(+)-馬錢子鹼氟氯碘乙酸鹽，可以得到(+)-氟氯碘甲烷（ee 63.3%）。[4]
參考文獻[編輯]
- ^ Haszeldine, Robert N. Polyhalomethanes. 1955. US 2716668.
- ^ 2.0 2.1 Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X （英語）.
- ^ A. Cuisset, J. R. Aviles Moreno, T. R. Huet, D. Petitprez, J. Demaison, J. Crassous. The Chiral Molecule CHClFI: First Determination of Its Molecular Parameters by Fourier Transform Microwave and Millimeter-Wave Spectroscopies Supplemented by ab Initio Calculations. The Journal of Physical Chemistry A. 2005-06-01, 109 (25): 5708–5716 [2021-11-02]. ISSN 1089-5639. doi:10.1021/jp0443658. （原始內容存檔於2021-11-05） （英語）.
- ^ Jeanne Crassous, Zhengjin Jiang, Volker Schurig, Prasad L. Polavarapu. Preparation of (+)-chlorofluoroiodomethane, determination of its enantiomeric excess and of its absolute configuration. Tetrahedron: Asymmetry. 2004-07, 15 (13): 1995–2001 [2021-11-02]. doi:10.1016/j.tetasy.2004.06.006. （原始內容存檔於2018-06-15） （英語）.
