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肉桂基溴

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肉桂基溴
别名 苯丙烯基溴
识别
CAS号 4392-24-9  checkY
26146-77-0(反式)  checkY
115117-88-9(顺式)  checkY
性质
化学式 C9H9Br
摩尔质量 197.07 g·mol−1
熔点 26—28 °C(299—301 K)(反式)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

肉桂基溴是一种有机溴化合物,化学式为C9H9Br,它存在顺、反异构体,其中,反式异构体更为常见。

肉桂基溴可由肉桂醇三溴化磷反应制得。[2]它和叠氮化钠反应,可以得到肉桂基叠氮化物。[3][4]它和乙酸钾DMSO中反应,可以得到乙酸肉桂酯[5]

参考文献

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  1. ^ Y. Tamaru, Y. Furukawa, M. Mizutani, O. Kitao, Z. Yoshida. Diastereoselective .alpha. allylation of secondary and tertiary thioamides via thio-Claisen rearrangement. A structural proof of Z secondary thioamide dianions and Z tertiary thioamide anions. The Journal of Organic Chemistry. 1983-10, 48 (21): 3631–3639 [2023-03-25]. ISSN 0022-3263. doi:10.1021/jo00169a003. (原始内容存档于2023-03-25) (英语). 
  2. ^ Hong-Fa Wang, Lin-Na Guo, Zhi-Bo Fan, Tian-Hua Tang, Weiwei Zi. Gold-Catalyzed Formal Hexadehydro-Diels–Alder/Carboalkoxylation Reaction Cascades. Organic Letters. 2021-04-02, 23 (7): 2676–2681 [2023-03-25]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c00581. (原始内容存档于2022-11-20) (英语). 
  3. ^ Lachlan Campbell-Verduyn, Philip H. Elsinga, Leila Mirfeizi, Rudi A. Dierckx, Ben L. Feringa. Copper-free ‘click’: 1,3-dipolar cycloaddition of azides and arynes. Organic & Biomolecular Chemistry. 2008, 6 (19): 3461 [2023-03-25]. ISSN 1477-0520. doi:10.1039/b812403e (英语). 
  4. ^ Feng Shi, Jesse P. Waldo, Yu Chen, Richard C. Larock. Benzyne Click Chemistry: Synthesis of Benzotriazoles from Benzynes and Azides. Organic Letters. 2008-06-01, 10 (12): 2409–2412 [2023-03-25]. ISSN 1523-7060. PMC 3750119可免费查阅. PMID 18476707. doi:10.1021/ol800675u. (原始内容存档于2023-03-25) (英语). 
  5. ^ Natan J. W. Straathof, Sten E. Cramer, Volker Hessel, Timothy Noël. Practical Photocatalytic Trifluoromethylation and Hydrotrifluoromethylation of Styrenes in Batch and Flow. Angewandte Chemie International Edition. 2016-12-12, 55 (50): 15549–15553 [2023-03-25]. doi:10.1002/anie.201608297. (原始内容存档于2023-03-25) (英语).