苯甲硒醇
| 苯甲硒醇 | |
|---|---|
| 别名 | 苄硒醇 |
| 识别 | |
| CAS号 | 16645-12-8 
|
| 性质 | |
| 化学式 | C7H8Se |
| 摩尔质量 | 171.1 g·mol−1 |
| 沸点 | 101.5—102.5 °C（374.6—375.6 K）（22 torr）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
苯甲硒醇是一种有机硒化合物，化学式为C7H8Se，它在空气中容易氧化。[1]
合成
[编辑]苯甲硒醇可由氯化苄和硒氢化钠反应制得[2]，或二苄基二硒经氢化铝锂[3]或硼氢化钠[4]还原后酸化得到。
参考文献
[编辑]- ^ 1.0 1.1 Rheinboldt, Heinrich; Giesbrecht, Ernesto. Unsymmetrical diselenides. Chemische Berichte, 1952. 85. 357-368.
- ^ Alfredo Ricardo Marques de Oliveira, Leandro Piovan, Fabio Simonelli, Anderson Barison, Maria de Fatima C. Santos, Murilo Belini Marcondes de Mello. A 77Se NMR study of elemental selenium reduction using NaBH4. Journal of Organometallic Chemistry. 2016-03, 806: 54–59 [2023-03-12]. doi:10.1016/j.jorganchem.2016.01.028. （原始内容存档于2018-06-28） （英语）.
- ^ Antonella Capperucci, Alessandra Petrucci, Cristina Faggi, Damiano Tanini. Click Reaction of Selenols with Isocyanates: Rapid Access to Selenocarbamates as Peroxide‐Switchable Reservoir of Thiol‐Peroxidase‐Like Catalysts. Advanced Synthesis & Catalysis. 2021-09-07, 363 (17): 4256–4263 [2023-03-12]. ISSN 1615-4150. doi:10.1002/adsc.202100611. （原始内容存档于2023-03-12） （英语）.
- ^ Ying Zhong, Xiaoming Xu, Qingzhao Xing, Song Yang, Jing Gou, Ziwei Gao, Binxun Yu. Furfuryl Cation Induced Three-Component Reaction to Synthesize Triazole-Substituted Thioesters: Furfuryl Cation Induced Three-Component Reaction to Synthesize Triazole-Substituted Thioesters. European Journal of Organic Chemistry. 2020-06-16, 2020 (22): 3251–3256 [2023-03-12]. doi:10.1002/ejoc.202000299 （英语）.