氟化磷酸盐

氟化磷酸盐^[1]是由氟离子（F−
）和磷酸根（PO3−
4）构成的混合阴离子化合物。自然界中常见的氟化磷酸盐矿物有氟磷灰石（氟化三磷酸五钙，Ca₅(PO₄)₃F）、氟磷镁石（英语：Wagnerite）（(Mg,Fe)₂PO₄F）等。人工合成的M^IM^IIPO₄F（M^I=Na, Li；M^II=Fe, Mn, Co, Ni）可用于电化学的正极材料。^[2]

合成[编辑]

氟化磷酸盐可由磷酸二氢铵-氟化钠和金属盐体系的固相法合成，或通过含磷酸-氟化钠（氢氟酸^[3]）的水热体系反应得到。^[4]反应中也会加入其它试剂，如硼酸作为矿化剂。^[5]

参考文献[编辑]

^ 中国化学会无机化学命名原则 1980. pp. 19. (III)混盐和复盐. “……在名称中将分子量较小者放在前面”
^ 郑寅. 钠离子电池正极材料氟化磷酸盐的物理和电化学性质. 厦门大学. 2014.
^ Gwenaël Corbel, Georges Courbion, Françoise Le Berre, Marc Leblanc, Jean-Marc Le Meins, Vincent Maisonneuve, Nicolas Mercier. Synthesis from solutions and properties of various metal fluorides and fluoride salts. Journal of Fluorine Chemistry. 2001-02, 107 (2): 193–198 [2022-05-29]. doi:10.1016/S0022-1139(00)00358-4. （原始内容存档于2019-11-01）（英语）.
^ Brian L. Ellis, W. R. Michael Makahnouk, W. N. Rowan-Weetaluktuk, D. H. Ryan, Linda F. Nazar. Crystal Structure and Electrochemical Properties of A 2 MPO 4 F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni). Chemistry of Materials. 2010-02-09, 22 (3): 1059–1070 [2022-05-29]. ISSN 0897-4756. doi:10.1021/cm902023h. （原始内容存档于2022-06-03）（英语）.
^ Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C. 2020, 8 (14): 4965–4972 [2022-05-29]. ISSN 2050-7526. doi:10.1039/D0TC00281J （英语）.

[1] 中国化学会无机化学命名原则 1980. pp. 19. (III)混盐和复盐. “……在名称中将分子量较小者放在前面”

[2] 郑寅. 钠离子电池正极材料氟化磷酸盐的物理和电化学性质. 厦门大学. 2014.

[3] Gwenaël Corbel, Georges Courbion, Françoise Le Berre, Marc Leblanc, Jean-Marc Le Meins, Vincent Maisonneuve, Nicolas Mercier. Synthesis from solutions and properties of various metal fluorides and fluoride salts. Journal of Fluorine Chemistry. 2001-02, 107 (2): 193–198 [2022-05-29]. doi:10.1016/S0022-1139(00)00358-4. （原始内容存档于2019-11-01）（英语）.

[4] Brian L. Ellis, W. R. Michael Makahnouk, W. N. Rowan-Weetaluktuk, D. H. Ryan, Linda F. Nazar. Crystal Structure and Electrochemical Properties of A 2 MPO 4 F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni). Chemistry of Materials. 2010-02-09, 22 (3): 1059–1070 [2022-05-29]. ISSN 0897-4756. doi:10.1021/cm902023h. （原始内容存档于2022-06-03）（英语）.

[5] Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C. 2020, 8 (14): 4965–4972 [2022-05-29]. ISSN 2050-7526. doi:10.1039/D0TC00281J （英语）.

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