丙酸锆

丙酸锆
别名	四丙酸锆
识别
CAS号	25710-96-7 ; 12562-38-8
性质
化学式	C12H20O8Zr
摩尔质量	383.51 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

丙酸锆是锆形成的丙酸盐，化学式为Zr(CH₃CH₂COO)₄。它可由四氯化锆和丙酸反应，经ZrCl₂(CH₃CH₂COO)₂中间体，加热后制得。^[1]它在水中水解，生成ZrO(CH₃CH₂COO)₂。^[2]它在丙醇中和二氧化锗及氢氧化钾溶液于180 °C进行溶剂热反应，可以得到K₂ZrGe₂O₇。^[3]

参考文献[编辑]

^ J. Ludwig, Donald Schwartz. Reactions of zirconium(IV) chloride with some aliphatic acids. Inorganic Chemistry. 1970-03, 9 (3): 607–611 [2021-07-03]. ISSN 0020-1669. doi:10.1021/ic50085a034 （英语）.
^ Rc Paul, Ob Baidya, Rc Kumar, R Kapoor. Zirconium(IV) carboxylates. Australian Journal of Chemistry. 1976, 29 (7): 1605 [2021-07-03]. ISSN 0004-9425. doi:10.1071/CH9761605 （英语）.
^ Pilar Pertierra, Miguel A. Salvado, Santiago Garcia-Granda, Camina Trabajo, J.R. Garcia, Anatoly I. Bortun, Abraham Clearfield. Synthesis, Characterization, and X-Ray Powder Structure of K2ZrGe2O7. Journal of Solid State Chemistry. 1999-11, 148 (1): 41–49 [2021-07-03]. doi:10.1006/jssc.1999.8332. （原始内容存档于2018-06-02）（英语）.

[1] J. Ludwig, Donald Schwartz. Reactions of zirconium(IV) chloride with some aliphatic acids. Inorganic Chemistry. 1970-03, 9 (3): 607–611 [2021-07-03]. ISSN 0020-1669. doi:10.1021/ic50085a034 （英语）.

[2] Rc Paul, Ob Baidya, Rc Kumar, R Kapoor. Zirconium(IV) carboxylates. Australian Journal of Chemistry. 1976, 29 (7): 1605 [2021-07-03]. ISSN 0004-9425. doi:10.1071/CH9761605 （英语）.

[3] Pilar Pertierra, Miguel A. Salvado, Santiago Garcia-Granda, Camina Trabajo, J.R. Garcia, Anatoly I. Bortun, Abraham Clearfield. Synthesis, Characterization, and X-Ray Powder Structure of K2ZrGe2O7. Journal of Solid State Chemistry. 1999-11, 148 (1): 41–49 [2021-07-03]. doi:10.1006/jssc.1999.8332. （原始内容存档于2018-06-02）（英语）.

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