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2,2-二甲基環氧乙烷

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2,2-二甲基環氧乙烷
別名 氧化異丁烯
甲基環氧丙烷
識別
CAS號 558-30-5  checkY
PubChem 11208
SMILES
 
  • O1CC1(C)C
性質
化學式 C4H8O
摩爾質量 72.11 g·mol−1
沸點 51.5 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

2,2-二甲基環氧乙烷是一種有機化合物,化學式為C4H8O,它是1,2-二甲基環氧乙烷同分異構體。它在鑭系金屬配合物的催化下可以和二氧化碳發生環加成反應,生成 異丁烯碳酸酯。[2][3]

參考文獻

[編輯]
  1. ^ House, Herbert O. The Rearrangement of Aliphatic Ethylene Oxides. Journal of the American Chemical Society (American Chemical Society (ACS)). 1955, 77 (19): 5083–5089. ISSN 0002-7863. doi:10.1021/ja01624a040. 
  2. ^ Wang, Wen-Min; Qiao, Na; Xin, Xiao-Yan; Wu, Zhi-Lei; Cui, Jian-Zhong. Octanuclear Ln(III)-Based Clusters Assembled by a Polydentate Schiff Base Ligand and a β-Diketone Co-Ligand: Efficient Conversion of CO2 to Cyclic Carbonates and Large Magnetocaloric Effect. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-19, 23 (1): 87–95. ISSN 1528-7483. doi:10.1021/acs.cgd.2c00746. 
  3. ^ Wang, Wen-Min; Cheng, Rui-Rui; Wu, Zhi-Lei; Cui, Jian-Zhong. Bifunctional Lanthanide-Based Coordination Polymers: Conversion of CO2 and Highly Selective Luminescence Sensing for Acetylacetone. Inorganic Chemistry (American Chemical Society (ACS)). 2023-08-31, 62 (37): 14902–14911. ISSN 0020-1669. doi:10.1021/acs.inorgchem.3c01626.